比较 ABS、PLA、PETG、TPU、ASA、PBT 和尼龙长丝:主要差异解释
选择最佳的 3D 打印丝材或工程塑料是一个根据您的项目需求(强度、灵活性、耐热性、表面光洁度等)决定的过程。桌面3D打印和轻量化工程中使用最广泛的塑料是PLA、ABS、PETG、TPU、ASA、PBT和尼龙。每种材料都具有独特的机械、热和化学特性,这些特性不仅影响适印性,还影响成品部件的功能和寿命。
下面,您将找到这些材料的详细比较,包括它们的特性、易于打印、成本、耐用性和典型应用。
1。什么是 ABS 塑料?
ABS 代表全称丙烯腈丁二烯苯乙烯。它是一种流行的工程热塑性塑料,因其耐用性、强度和易于加工而受到认可。 ABS 属于非晶态塑料家族,广泛应用于消费和工业应用。由于 ABS 具有均衡的特性,乐高积木、汽车零部件、外壳和各种日常用品等物品通常由 ABS 制成。
ABS塑料成分
ABS 是由三种单体制成的三元共聚物:丙烯腈、丁二烯和苯乙烯。每个组件都具有特定的特性:
- 丙烯腈可提高耐化学性和热稳定性。
- 丁二烯具有韧性和抗冲击性。
- 苯乙烯可增加刚性并提供光滑的表面光洁度。
这三种成分的比例可以调整,使制造商能够针对不同用途微调最终性能。为了达到特定要求,还经常加入添加剂和着色剂。
ABS 长丝特性
物理和机械性能
- 密度:约 1.04–1.07 g/cm3。
- 拉伸强度:中等,通常在 40-50 MPa 范围内。
- 弯曲强度:高于 PLA,具有更高的灵活性。
- 抗冲击性:以其承受冲击和跌落的能力而闻名。
- 硬度:坚硬、中等硬度;这就是乐高积木如此耐用的原因。
- 屈服强度:足以满足许多承载应用的需要,但不如某些工程塑料那么高。
热性能
- 耐热性:ABS 的工作温度范围约为 -40°C 至 70–105°C,具体取决于牌号和配方。
- 玻璃化转变温度:通常约为 105°C。
- 热稳定性:在较高温度下比 PLA 更能保持形状和机械强度。
- 工作温度:可以在许多中等热量的环境中运行。
电气特性
- 电绝缘:ABS 被认为是良好的电绝缘体,使其适用于各种电气外壳和组件。
其他特征
- 可加工性:易于切割、钻孔、铣削和打磨。易于接受油漆和粘合剂。
- 吸水率:低,但不为零。随着时间的推移,ABS 会吸收少量的水分。
- 表面光洁度:光滑,可抛光或化学平滑以获得光滑的外观。
- 紫外线防护:有限;除非稳定,否则 ABS 会随着长时间的紫外线照射而变黄和降解。
适印性
ABS 需要更高的打印温度 (220–260°C) 和加热床 (80–110°C)。它对温度波动和气流很敏感,因此几乎必须使用外壳来防止变形和破裂。 ABS 在打印过程中会散发出明显的烟雾,因此适当的通风至关重要。
ABS 塑料的优缺点
优点:
- 刚性、韧性和抗冲击性之间具有良好的平衡。
- 可以注塑、机加工和 3D 打印(小心)。
- 在较宽的温度范围内保持性能。
- 易于涂漆、粘合和完成。
- 有多种形式和尺寸可供选择(片状、棒状、丝状)。
- 对饮用水系统无毒且安全。
缺点:
- 在快速冷却过程中或在 3D 打印过程中暴露在气流中时可能会变形或破裂。
- 比 PLA 需要更高的加工温度。
- 加热时会发出明显的烟雾。
- 与更柔韧的塑料相比,它更脆,尤其是在反复受力的情况下。
- 无添加剂时,抗紫外线性能较差。
- 承载能力低,导致滑动或承载应用中的摩擦力较高。
ABS 塑料类型
ABS 有多种牌号和配方,包括:
- 通用 ABS:注塑成型和原型制作的标准性能平衡。
- 高抗冲 ABS:增加丁二烯含量以提高抗冲击性。
- 可电镀 ABS:经过改性,可轻松进行金属表面电镀。
- 阻燃 ABS:增强电气和电子应用的安全性。
- ABS 共混物:有时与其他塑料(如聚碳酸酯)混合以提高特定领域的性能。
ABS 塑料应用
ABS 存在于无数的产品和行业中:
- 玩具:最著名的是乐高积木。
- 汽车:内饰、仪表板组件和车身部件。
- 消费电子产品:遥控器、计算机和电器的外壳。
- 管道:管道、配件和阀门。
- 结构:墙壁插座、面板和防护罩。
- 原型制作:常用于 CNC 加工和 3D 打印原型。
- 定制汽车零件:侧裙、扰流板和其他车身改装。
- 板材和棒材:用于各个工业领域的制造和机加工。
ABS 塑料成本
ABS被认为是一种低成本的工程塑料。对于 3D 打印,ABS 长丝线轴的价格通常与 PLA 类似,约为每公斤 20 美元。与许多其他工程聚合物相比,片材、棒材和模制部件的价格也更实惠。它的可用性和成本效益使其成为小规模和大规模制造的常见选择。
ABS 塑料寿命和回收
ABS 专为长期耐用而设计。在许多应用中,ABS 零件可以使用数十年,尤其是在不暴露于严酷的紫外线或极端条件下的情况下。例如,管道系统中的 ABS 管道和配件的使用寿命可达 50 年或更长。在回收方面,ABS 属于塑料类别#7(其他)。虽然它在技术上是可回收的,但实际回收率仍然很低,通常低于 1%。大多数市政项目不接受 ABS,因此大部分最终都会被填埋。与 PLA 不同,ABS 不可生物降解。
2。什么是PLA塑料?
PLA 代表全聚乳酸,是一种通过乳酸聚合产生的热塑性脂肪族聚酯。乳酸本身源自可再生资源,如玉米、甘蔗或其他植物材料。 PLA 因其生物相容性和生物降解性而受到认可,使其成为领先的环保塑料。当在适当的堆肥条件下丢弃时,PLA 会被微生物分解成二氧化碳和水,对环境的影响最小。它源自植物材料,使其成为石油衍生塑料的流行替代品。
PLA长丝组合物
PLA 由乳酸合成,乳酸是通过发酵植物淀粉(通常来自玉米、甜菜或甘蔗)产生的。该过程包括将这些植物材料分解成葡萄糖,将糖发酵成乳酸,然后将乳酸聚合成聚乳酸链。使用两种主要的聚合方法:直接缩合和开环聚合。由此产生的 PLA 可以使用与传统塑料相同的设备进行加工,例如挤出、注塑和吹塑。
PLA 属性
物理特性
- 密度:PLA 的密度通常约为 1.24 g/cm3。
- 外观:通常是透明到半透明,但有多种颜色可供选择。
- 气味:无味且无毒,适合食品相关应用。
- 吸水性:PLA 具有中等亲水性,因此会吸收一些水分,这可能会影响打印质量和存储。
机械性能
- 强度:PLA 具有良好的刚性和中等强度,但与 PETG 或 ABS 等其他 3D 打印线材相比更脆。对于非承重应用,它可以很好地保留细节和形状。
- 硬度:虽然 PLA 相对较硬,但它也更容易在压力下折断、断裂而不是弯曲。
- 拉伸强度:PLA 的拉伸强度约为 50–70 MPa,足以用于装饰和轻型功能部件。
- 屈服强度:表现出中等屈服强度,但与延展性较好的塑料相比,其伸长率较低。
- 可加工性:PLA 易于切割、打磨和钻孔,但需要适当的支撑以防止破裂。
热性能
- 耐热性:PLA 在低温下开始软化。玻璃化转变温度约为55-60°C,熔化温度约为190-220°C。这限制了其在高温环境中的使用,例如炎热的汽车内饰或洗碗机。
- 工作温度:最适合温度低于 50°C 的应用,因为 PLA 在暴露于较高温度时会变形或失去强度。
电气特性
- 绝缘:PLA 与其他塑料类似,具有良好的绝缘性能,使其成为外壳和非导电部件的安全选择。
抗紫外线和环境能力
- 紫外线防护:PLA 不太能抵抗紫外线辐射,长时间暴露在阳光下会降解。
- 生物降解性:在工业堆肥条件下,PLA 可分解为水和二氧化碳,提供可持续的报废选择。然而,在家庭堆肥或垃圾填埋场中,这个过程要慢得多。
适印性
PLA 非常宽容:它可以轻松粘附到大多数床上,很少变形,并且无需外壳或加热床即可良好打印。它可以轻松处理悬垂和精细细节,使其成为复杂模型、玩具和装饰物品的首选。
PLA 长丝的优缺点
优点:
- 非常容易打印
- 多种颜色和特殊饰面(丝绸、哑光、夜光)
- 价格实惠且广泛使用
- 良好的表面质量
缺点:
- 不适合高温或户外使用
- 在紫外线照射下会降解
- 易碎,在撞击下容易碎裂
- 没有工业设施就无法真正堆肥
PLA 塑料类型
PLA 有多种变体可以满足不同的需求:
- 标准 PLA:最常见,用于一般印刷和包装。
- 高温 PLA:经过改良,具有更高的耐热性,可在较温暖的环境中使用。
- 混合 PLA:与木纤维、大麻或其他生物聚合物等添加剂混合,以改变质地、机械性能或外观。
- 柔性 PLA:含有增塑剂或混合聚合物以提高灵活性。
- 医用级 PLA:经过纯化,可用于缝合线、植入物和药物输送装置等生物医学应用。
- 透明 PLA:为了光学透明度而生产,可用于包装。
PLA 长丝应用
由于其多功能性和环境优势,PLA 的应用范围正在不断扩大:
- 3D 打印:桌面 3D 打印机中最受欢迎的耗材,尤其适合初学者,因为它易于使用且打印效果清晰。
- 食品包装:用于一次性杯子、盘子、餐具和食品容器,受益于其安全性和可堆肥性。
- 农业:存在于地膜、种子包衣和遮阳网中,使用后会降解,减少农业废物。
- 生物医学:由于其生物相容性,可用于手术缝合线、药物输送系统、组织工程和可生物降解植入物。
- 纺织品:采用环保面料,具有透气性、抗菌性和阻燃性。
- 能源行业:用于制造生物燃料、燃料电池膜和其他可再生能源设备。
- 一般包装:应用于重视短期使用和可堆肥性的各种薄膜和容器。
PLA 长丝成本
PLA 通常价格实惠,价格接近其他常见 3D 打印耗材。虽然由于发酵过程和农业采购,早期生产成本较高,但扩大生产规模降低了价格。在零售方面,用于 3D 打印机的 PLA 长丝通常每公斤 20 美元左右,业余爱好者和专业人士都可以买到。随着生产技术的进步,成本有望进一步降低。
PLA 塑料寿命和回收
PLA 产品在免受热、紫外线辐射和过度潮湿的环境中效果最佳。在室内,PLA 打印件可以保存数年,但暴露在高温或阳光下可能会导致快速降解或翘曲。在生物医学用途中,PLA 的受控降解是一个好处,可以逐渐被人体吸收。
PLA 可在提供必要热量和湿度的专业工业设施中进行堆肥。在这些环境中,它可能会在几个月到一年内崩溃。然而,在标准垃圾填埋场或家庭堆肥条件下,分解速度极其缓慢,与传统塑料类似。 PLA 与其他“其他”塑料一起被归为第七类塑料,这通常意味着它在大多数市政系统中不会被分离回收。一些专门项目单独收集和处理 PLA,但广泛的回收基础设施仍在开发中。正确的处置需要使用工业堆肥来实现 PLA 的环境效益。
3。什么是PETG塑料?
PETG塑料代表的是完全由聚对苯二甲酸乙二醇酯改性而成。它是一种透明的非结晶共聚酯,由精对苯二甲酸 (PTA)、乙二醇 (EG) 和 1,4-环己烷二甲醇 (CHDM) 缩聚而成。与标准 PET 相比,在 PET 基料中添加乙二醇 (CHDM) 赋予 PETG 独特的性能,例如改进的透明度、抗冲击性和可加工性。作为一种热塑性聚酯,PETG 广泛用于需要韧性、透明性和耐化学性的应用。它已成为产品包装、建筑、医疗器械,尤其是3D打印的首选材料。
PETG塑料成分
PETG 的分子结构是通过引入 1,4-环己烷二甲醇作为共聚单体而设计的,这破坏了 PET 典型的规则结晶模式。这导致无定形聚合物具有高透明度和增强的加工性能。 PETG 中的最佳 CHDM 含量范围为 30% 至 40%,平衡机械强度、柔韧性和热稳定性。这种定制的成分使 PETG 将 PET 的最佳特性与改进的成型性和韧性结合起来。
PETG 塑料特性
物理特性
- 透明度:PETG 具有高透光率,通常超过 91%,因此适合要求透明度的应用。
- 密度:约 1.27 g/cm3,与传统 PET 类似。
- 外观:透明、有光泽的片材、薄膜、细丝或模制部件。
机械性能
- 韧性:PETG 的韧性是普通丙烯酸树脂的 15-20 倍,是抗冲改性丙烯酸树脂的 5-10 倍。
- 拉伸强度:一般为50-60 MPa,断裂伸长率可达180%。
- 抗冲击性:冲击强度可达 85 kJ/m²,使 PETG 能够承受跌落和机械冲击。
- 弯曲模量:通常在 2060–2160 MPa 之间。
- 屈服强度:室温下范围为 50.3 至 53.1 MPa。
- 硬度:洛氏硬度介于 106 到 116 之间。
热性能
- 玻璃化转变温度:约 70–80°C,高于 PLA,适合暴露于中等热量的零件。
- 使用温度:PETG 在低至 -40°C 和高达约 80°C–120°C 的温度下仍能保持机械性能,具体取决于配方。
- 熔点:低于 PET,更容易热成型和 3D 打印。
耐化学性
- 一般耐受性:PETG 可耐受大多数酸、碱和有机溶剂,并且在室温下不易被水降解。
- 耐水解性:在潮湿条件下稳定,适合医疗和食品接触用途。
其他属性
- 抗紫外线:含有紫外线吸收剂,有助于在阳光下保持韧性和透明度,适合户外使用。
- 吸水性:吸水性较低,但与许多热塑性塑料一样,应干燥存放才能获得最佳性能(尤其是在 3D 打印之前)。
- 电绝缘:为电子外壳和托盘提供良好的绝缘性能。
- 可加工性:可锯切、钻孔、模切、冲孔、铆接和铣削,不会破裂或泛白。热成型反应良好,可冷弯。
适印性
PETG 打印温度为 220–250°C,床温为 70–90°C。它通常比 ABS 更容易打印,但在某些构建表面上容易拉丝和过度粘附。它不需要外壳,并且翘曲小于 ABS。水分管理对于获得最佳效果非常重要。
PETG 塑料的优缺点
优点:
- 强度、柔韧性和易于印刷的良好平衡
- 耐化学物质和紫外线照射
- 比 ABS 更少翘曲
- 有多种颜色可供选择,包括透明和半透明选项
缺点:
- 如果调音不当,可能会拉丝和渗出
- 表面光洁度比 PLA 或 ABS 更有光泽
- 对某些床的粘附力太强(可能会损坏表面)
- 不像 PLA 那样坚硬,也不像 ABS 那样耐热
PETG 塑料类型
- 标准 PETG:具有良好的透明度、韧性,并且易于加工,适合一般用途。
- 增韧 PETG:用添加剂进行改性,可增强需要更高韧性的应用的抗冲击性。
- 抗紫外线 PETG:采用适合户外应用的紫外线稳定剂配制而成,可防止黄变和脆化。
- 增强型 PETG:含有玻璃纤维或碳纤维,可提高机械和热性能,用于要求苛刻的工业和工程环境。
- 抗静电 PETG:专为需要静电控制的电子包装和托盘而设计。
- 医疗级 PETG:在严格条件下生产,用于医疗器械和包装。
PETG 塑料应用
PETG 兼具强度、透明度和耐化学性,使其在不同行业中广受欢迎:
- 包装:用于食品、饮料、药品和化妆品容器,例如瓶子、罐子和泡罩包装。它的清晰度可以展示产品,同时保护它们。
- 电子产品:外壳、托盘和屏幕盖受益于 PETG 的绝缘和耐化学性能。
- 建筑和建筑:用于室内外标牌、展示板、隔断和装饰表面,兼具美观性和耐用性。
- 医疗设备:非常适合过滤器、连接器、管道、泵和包装,满足卫生和安全要求。
- 汽车:因其韧性和耐候性而用于车头灯罩、内饰和防护板。
- 3D 打印:因其易于打印、层间附着力强、低翘曲以及适用于原型和功能部件而受到青睐。
- 信用卡:PETG 目前用于信用卡和银行卡,与 PVC 相比,具有灵活性、耐用性和环保优势。
- 收缩膜:用于包装复杂形状的高性能收缩包装,具有高透明度和适印性。
PETG 塑料成本
PETG的成本体现了其先进的性能和加工优势。在全球市场上,PETG原材料的成本通常高于标准PET或PLA,价格约为18-22元/公斤,而PET为12元/公斤。在 3D 打印中,PETG 长丝通常仅比 PLA 贵一点,典型的线轴价格在每公斤 22 至 30 美元之间。特种 PETG 等级和增强版本的成本会更高。随着产能的增加和需求的增长,价格继续变得更具竞争力。
PETG 塑料寿命和回收
PETG 产品经久耐用。它们可以在室内和室外环境中承受多年的使用,防止泛黄、开裂或失去韧性。由于其耐候性和抗紫外线性,PETG 在温度波动和阳光照射下仍能保持机械完整性。然而,由于 PETG 比某些替代品更容易划伤,因此建议进行表面护理。
PETG 不可生物降解,如果丢弃不当,将在垃圾填埋场中持续存在数十年。然而,它是完全可回收的,并且可以通过机械回收和(不太常见)化学回收进行再加工。机械回收是主要途径,PETG 废物被粉碎并重新挤压成新产品。化学解聚是可能的,但成本仍然很高且不太普遍。回收PETG有助于减少资源消耗和环境影响。在某些地区,PETG 与 PET 一起被接受在回收流程中,但当地的能力可能有所不同。
4。什么是TPU塑料?
什么是TPU塑料? TPU 代表全形式热塑性聚氨酯。它是热塑性弹性体 (TPE) 家族的一员,以其独特的柔韧性、弹性和韧性组合而著称。 TPU 由具有交替软硬链段的线性嵌段共聚物组成,从而形成一种将橡胶的拉伸性和弹性与塑料的加工性结合在一起的材料。这种材料因其适应性而受到特别重视,因为它可以被配制为柔软且有弹性或更坚硬,同时保持橡胶般的弹性和耐用性。
TPU塑料成分
TPU由二异氰酸酯(如MDI、TDI或HDI)、高分子多元醇(聚酯、聚醚、聚己内酯或聚碳酸酯)和扩链剂(短链二醇)聚合合成。硬链段通常基于二异氰酸酯,提供结构完整性和强度,而软链段(多元醇)则提供柔韧性和低温性能。硬链段与软链段的比例以及所用多元醇和二异氰酸酯的类型可以精确调节 TPU 的性能。
TPU按成分分类的主要类别:
- 芳香族 TPU:采用芳香族二异氰酸酯(例如 MDI),机械强度高,但抗紫外线能力较差。
- 脂肪族 TPU:采用脂肪族二异氰酸酯(例如 HDI、IPDI)配制而成,具有卓越的紫外线稳定性和透明度。
- 软链段类型:聚酯、聚醚、聚己内酯和聚碳酸酯变体,每种都具有不同的性能特征。
TPU 塑料特性
物理特性
- 密度:通常范围为 1.14 至 1.22 g/cm3。
- 透明度:某些牌号(尤其是聚碳酸酯牌号)具有出色的透明度。
- 表面:可以是光面或哑光,具有天然橡胶感。
机械性能
- 硬度:范围广泛,从 Shore A 60 到 Shore D 80,在各个级别都能保持弹性。
- 拉伸强度:一般为30-65 MPa,断裂伸长率通常超过600-800%。
- 撕裂强度:高抗撕裂和抗弯曲疲劳能力。
- 耐磨性:优于天然橡胶,耐磨性高出 2-10 倍。
- 弹性恢复:即使在显着变形后也能保持原始形状。
热性能
- 工作温度:在 -40°C 至 90°C 范围内保持灵活(某些等级低至 -50°C 或高达 120°C)。
- 玻璃化转变温度:低,可在零度以下的温度下实现灵活性。
- 耐热性:可在高达 80–100°C 的温度下连续运行,某些特种牌号可以承受更高的温度。
耐化学性
- 耐油性:聚酯基 TPU 具有优异的耐油和耐油脂性能。
- 耐水和耐水解性:聚醚基 TPU 耐水解,是潮湿环境的首选。
- 化学稳定性:可承受多种燃料、润滑剂和清洁剂。
环境和电气特性
- 耐候性:脂肪族TPU可耐受紫外线照射,不易黄变;芳香族 TPU 在户外可能会泛黄。
- 生物相容性:许多医用级产品都是无毒的,适合皮肤或内部接触。
- 吸水率:聚醚 TPU 吸水率较低,可提高尺寸稳定性。
- 电绝缘:适用于电缆护套及相关用途。
可加工性
- 加工:可以注塑、挤出、吹塑或 3D 打印。支持切割、焊接、粘接等多种后处理方式。
适印性
TPU 需要仔细调整,通常在 200–230°C 下打印,床温度为 40–60°C。柔性长丝受益于缓慢的打印速度和直接驱动挤出机。鲍登设置可以工作,但可能需要非常慢的速度和仔细的回缩调整。 TPU具有吸湿性,应保持干燥。
TPU 优点和缺点
优点:
- 灵活耐用
- 减震和减震
- 非常适合定制、可穿戴或柔软组件
- 良好的耐化学性和耐磨性
缺点:
- 打印起来很棘手,尤其是在 Bowden 挤出机上
- 需要低速和最小的回缩
- 易受潮
- 不适合高负载结构件
TPU 塑料类型
- 聚酯TPU:强度高,耐磨性和耐油性优异,耐水解性较低;广泛用于鞋底和机械零件。
- 聚醚 TPU:优异的柔韧性、耐水解性和耐微生物性,适用于防水产品和医疗器械。
- 聚己内酯TPU:兼具耐磨性和耐水解性;用于密封件、医疗部件和高端应用。
- 聚碳酸酯TPU:出色的透明度、耐候性和耐化学性;存在于光学和医疗设备中。
- 脂肪族 TPU:具有出色的紫外线稳定性且不黄变;用于户外透明薄膜和汽车漆面保护。
- 特种牌号:包括阻燃、抗静电和生物基 TPU,以及用于柔软、轻质部件的发泡变体。
TPU 塑料应用
TPU 的适应性使其成为多种产品的主要材料:
- 鞋类:用于鞋底、装饰膜、缓冲元件和防水/透气膜。
- 汽车:用于仪表板、垫圈、软管、内饰和漆面保护膜。
- 消费电子产品:流行于手机壳、可穿戴手环和保护套。
- 医疗器械:由于具有生物相容性,可应用于导管、管材、伤口敷料和软假肢。
- 运动器材:用于柔性护具、鞋垫和充气产品。
- 工业部件:垫圈、密封件、滚筒、传送带和脚轮受益于 TPU 的耐磨性和耐化学性。
- 3D 打印:适合生产柔性零件、活动铰链、阻尼器和定制可穿戴物品。
- 薄膜和片材:应用于防水服装、户外装备和特种包装。
TPU 塑料成本
由于其专业化生产和性能,TPU 的成本高于许多普通塑料,但价格因牌号、硬度和添加剂而异。在 3D 打印市场中,标准 TPU 长丝的价格通常为每公斤 25 至 50 美元,医用或高性能类型的成本更高。对于注塑和挤出,价格取决于具体配方和订单数量,但与通用塑料相比,TPU 仍然是优质工程材料。
TPU 塑料寿命和回收
TPU 非常耐用,可承受多年的机械应力、弯曲和环境暴露。其出色的耐磨性和抗疲劳性意味着零件即使在反复弯曲或冲击下也能长时间使用。聚醚 TPU 耐水解,适合潮湿环境,而聚酯 TPU 在干燥、磨损条件下表现出色。长时间暴露于紫外线(对于芳香族等级)或暴露于与特定 TPU 配方不相容的刺激性化学物质可能会缩短使用寿命。
TPU 作为热塑性塑料完全可回收。废物或废料可以重新研磨和再加工,某些生产方法(例如 SLS 3D 打印)可以实现较高的粉末再利用率。虽然 TPU 不可生物降解,但某些牌号的配方更加环保,并且该材料越来越多地用于强调循环经济和可持续性的应用中。适当的收集和回收有助于最大限度地减少对环境的影响和资源消耗。
5。什么是 ASA 塑料?
什么是ASA塑料丝? ASA,全称丙烯腈苯乙烯丙烯酸酯,是一种合成热塑性树脂,由苯乙烯、丙烯腈和丙烯酸酯橡胶接枝共聚而成。 ASA 最初是为了将 ABS(丙烯腈丁二烯苯乙烯)的优点与 PMMA(聚甲基丙烯酸甲酯)的耐候性相结合而开发的,在户外环境中具有出色的性能。其结构具有“海岛”形态,其中SAN树脂形成连续相,橡胶为分散相,从而使材料不仅具有机械耐久性,而且对紫外线和潮湿等环境因素具有出色的抵抗力。
ASA塑料成分
ASA is a copolymer made from three main ingredients:
- Acrylonitrile:Contributes rigidity and chemical resistance.
- Styrene:Adds processability and surface gloss.
- Acrylic ester rubber:Responsible for impact resistance and long-term weatherability.
This blend can be tailored to achieve specific properties by adjusting the ratios or by blending with other polymers. ASA contains no heavy metals or hazardous substances, aligning with environmental safety standards.
ASA Plastic Properties
Physical and Mechanical Properties
- Density:Typically ranges from 1.05 to 1.09 g/cm³.
- Tensile Strength:Usually falls between 38 to 48 MPa.
- Impact Strength:Notched impact strength is about 480–580 J/m.
- Hardness:Maintains structural integrity and toughness at both high and low temperatures.
- Heat Resistance:Heat deflection temperature is 85–105°C at 1.86 MPa load, with some modified grades reaching higher.
- Operating Temperature:Usable from -20°C up to 75°C or higher, depending on grade.
- UV Protection:ASA resists yellowing, fading, and degradation after long-term exposure to sunlight.
- Creep Resistance:Exhibits low permanent deformation under sustained load, making it well-suited for load-bearing outdoor parts.
- Water Absorption:Low, which helps maintain structural stability outdoors.
- Machinability:Can be injection molded, extruded, blow molded, thermoformed, machined, welded, and bonded.
- Electrical Properties:Similar to ABS, with good insulating characteristics.
- Antistatic:Reduces surface dust accumulation.
Chemical and Thermal Properties
- Chemical Resistance:Withstands acids, alkalis, salt solutions, and many organic solvents. Not compatible with esters, ketones, aromatics, chlorinated compounds, or alcohols.
- Thermal Stability:Maintains color and mechanical strength after prolonged exposure to heat and sunlight.
- Flame Retardancy:Reaches UL94HB rating; burns slowly emitting a benzene/rubber odor.
Printability
ASA prints at 240–260°C, with a bed temperature of 90–110°C. While it warps less than ABS, an enclosure is still recommended for optimal results and to minimize cracking. ASA emits fewer odors and fumes than ABS but still benefits from ventilation.
ASA Plastic Types
ASA resin is manufactured in several grades, each suited for different processing methods and end uses:
- General Purpose:High fluidity and gloss, ideal for outdoor products (e.g., PW-957).
- Extrusion Grade:Designed for sheets, pipes, and antenna housings (e.g., PW-997S).
- Heat-Resistant Grade:Used for automotive components and heating appliance housings (e.g., PW-978B and PW-978D).
- Alloy Grades:Blended with other polymers such as PC (polycarbonate), PBT (polybutylene terephthalate), or AES for improved properties.
- Modified Grades:Enhanced for higher heat resistance, cold resistance, or better processability.
ASA Pros and Cons
Advantages:
- Outstanding UV and weather resistance
- High strength and impact resistance
- Low warping compared to ABS
- Retains color and gloss outdoors
Disadvantages:
- More expensive and less widely available than ABS
- Can be challenging to get good bed adhesion
- Requires high print temperatures and benefits from enclosure
ASA Plastic Applications
ASA’s weather and UV tolerance make it a top choice for outdoor and automotive products. Common applications include:
- Automotive:Exterior trims, mirror housings, radiator grilles, tailgates, lampshades, motorcycle panels, and recreational vehicle parts.
- Construction:Roofing tiles, wall cladding, door/window profiles, rain gutters, fencing, siding, and co-extruded profiles.
- Consumer Goods:Outdoor furniture, garden equipment, sports gear, leisure products (like spa pools and pool steps), and playground equipment.
- Electronics/Electrical:Housings for outdoor electrical boxes, antennas, satellite equipment, and durable household appliance covers (microwave ovens, dishwashers, vacuum cleaners).
- 3D Printing:Preferred for its printability, low warping, and strength, especially for items exposed to sunlight and weather.
ASA Plastic Cost
ASA pricing can be slightly above standard ABS but is becoming more competitive as adoption grows. The cost varies depending on the grade and supplier, but the price difference compared to ABS is decreasing. Costs are offset by reduced need for secondary surface treatments and the material’s long lifespan in outdoor use.
ASA Plastic Lifespan &Recycling
ASA maintains color, impact strength, and elongation at break even after 15 months of direct sunlight exposure. Many outdoor ASA parts remain functional and visually intact after years of service, such as garden benches and sports equipment. The material is recyclable, and scrap from processing or end-of-life products can be reprocessed, though its petroleum base limits its classification as a fully sustainable option. Overall, ASA delivers a long service life with minimal maintenance, especially in demanding environments.
6. What is PBT Plastic?
What is PBT filament? PBT stands for the full form Polybutylene Terephthalate, a semi-crystalline thermoplastic polyester. This material is renowned for its durability, dimensional stability, and resistance to heat and chemicals. PBT is widely used as an engineering plastic, especially in industries that demand reliable performance under mechanical and thermal stress. Its versatility allows it to be molded into complex shapes for a broad range of applications, including automotive, electrical, and consumer products.
PBT Plastic Composition
PBT belongs to the polyester family and is synthesized through the polycondensation of terephthalic acid (or its esters) and 1,4-butanediol. The resulting polymer chains form a semi-crystalline structure, imparting the material with its characteristic strength and resilience. PBT can be compounded with additives, colorants, or glass fibers to further adjust its mechanical or aesthetic properties. Notably, PBT does not achieve true optical transparency, but it can be produced in a wide variety of colors from natural white to vibrant shades, enhancing design flexibility.
PBT Plastic Properties
Physical Properties
- Density:PBT typically has a density around 1.31–1.35 g/cm³.
- Surface Hardness:The surface is hard and scratch-resistant, making it suitable for components that require long-lasting appearance.
- Color Range:Available in many hues, from white to bright colors.
Mechanical Properties
- Strength:PBT demonstrates high tensile and impact strength, suitable for mechanical and structural parts.
- Fatigue Resistance:Parts made from PBT maintain performance after repeated stress, with minimal fatigue failure.
- Dimensional Stability:The material resists deformation, even in high humidity or fluctuating temperatures.
- Machinability:PBT is easy to cut, laser machine, and injection mold, allowing precise manufacturing for intricate parts.
Thermal Properties
- Heat Resistance:PBT retains its properties from -40°C up to approximately 110°C in continuous use.
- Melting Point:The melting temperature is typically above 220°C, supporting applications that require exposure to moderate heat.
- Flame Retardancy:Flame retardant grades are available for electrical and electronic uses.
Chemical Resistance
- Excellent Resistance:PBT stands up well to many chemicals, including chlorine and caustic cleaning agents, making it a preferred choice for food processing and laboratory equipment.
- Low Water Absorption:Its semi-crystalline structure prevents significant moisture uptake, which preserves both mechanical and electrical properties.
Electrical Properties
- Insulation:PBT is a superior electrical insulator, suitable for high-frequency and high-humidity environments.
- Dielectric Strength:The material maintains insulation properties under various conditions, protecting sensitive components in electrical devices.
UV and Weather Resistance
- UV Stability:PBT offers good resistance to UV degradation, making it appropriate for parts exposed to sunlight or outdoor use.
Printability
PBT requires higher processing temperatures than PLA or ABS, often 240–270°C for the nozzle and 110–130°C for the bed. It can be compounded with glass fiber or other additives for enhanced performance. Warping can be a concern on large parts, so print environment and cooling must be managed carefully.
PBT Plastic Pros and Cons
Advantages
- High wear resistance ensures long-lasting parts in moving or abrasive environments.
- Excellent chemical resistance allows use in aggressive cleaning or industrial settings.
- Stable across a wide temperature range, with minimal deformation or warping.
- Low water absorption preserves dimensional accuracy and electrical insulation.
- Easily machinable and moldable for complex designs.
- Available in a wide selection of colors, supporting creative or functional design requirements.
- Recyclable and generally environmentally friendly in modern production contexts.
Disadvantages
- Not fully transparent; for applications needing transparency, other plastics must be blended in.
- Requires high processing temperatures, which can increase production costs due to the need for robust molds and precise temperature control.
- Large parts may be prone to warping during cooling, demanding careful quality control.
- Generally more expensive than commodity plastics like ABS, especially for double-shot or specialty applications.
- Limited availability in some profiles or custom shapes, given the complexity of the manufacturing process.
PBT Plastic Types
PBT is available in several grades and forms:
- Unfilled PBT:Used for general applications requiring a balance of strength and processability.
- Glass Fiber Reinforced PBT:Provides increased stiffness, strength, and dimensional stability for structural parts.
- Flame Retardant Grades:Specifically formulated for electrical and electronic components.
- Modified Blends:PBT can be combined with other polymers or additives to improve impact strength, UV resistance, or other characteristics.
- Color and Finish Variations:Manufactured in various colors and textures, from smooth to grainy, supporting diverse design needs.
PBT Plastic Applications
The robust properties of PBT make it a preferred material in many fields:
- Automotive:Used for connector housings, sensor casings, switches, and under-the-hood parts where resistance to heat and chemicals is vital.
- Electrical/Electronics:Common in sockets, switches, circuit breakers, and insulation for its electrical insulating abilities and flame resistance.
- Consumer Products:Popular in high-quality keycaps for mechanical keyboards, appliance housings, and small mechanical components.
- Industrial Machinery:Components like gears, bushings, and structural parts benefit from PBT’s strength and wear resistance.
- Food Processing Equipment:The material’s chemical and disinfectant resistance make it suitable for contact with food and cleaning fluids.
- Precision Parts:PBT sheets and rods are machined into parts requiring consistent dimensions and minimal warping.
PBT Plastic Cost
PBT generally commands a higher price than standard plastics such as ABS. The cost reflects the expense of raw materials, the complexity of processing (especially for double-shot or reinforced grades), and the demand for high-performance characteristics. Manufacturing processes for PBT require thicker, more durable molds and higher operating temperatures, further influencing cost. Despite these factors, PBT remains a cost-effective solution for applications needing superior performance, durability, and reliability.
PBT Plastic Lifespan &Recycling
PBT parts are known for their long service life, maintaining their mechanical and electrical properties even after years of use in demanding environments. Thanks to its wear resistance and chemical stability, PBT components often outlast those made from many other plastics. In terms of recycling, PBT is considered environmentally friendly and can be reprocessed, though as with many engineering plastics, recycling rates depend on local infrastructure and collection systems. Its durability means that PBT products often remain in use for extended periods before entering the recycling stream.
7. What is Nylon (Polyamide/PA) Plastic?
What is Nylon Plastic? Nylon, also known as Polyamide (PA), represents a family of synthetic polymers widely recognized for their strength, resilience, and versatility. Developed in the 1930s as an alternative to silk, nylon quickly found its place in both textiles and engineering applications. As a thermoplastic, nylon can be melted and reshaped multiple times without major chemical alteration. It is formed by linking monomers through amide bonds, resulting in a material that combines flexibility, high mechanical strength, and resistance to abrasion. Today, nylon is a staple in applications ranging from clothing fibers to mechanical gears and high-performance automotive parts.
Nylon PA Plastic Composition
Nylon plastics are built from long chains of polyamide resins. These chains are constructed via:
- Polycondensation of diamines and dibasic acids (as in PA66, from hexamethylene diamine and adipic acid)
- Or ring-opening polymerization of lactams (as in PA6, from caprolactam)
The defining feature of nylon’s structure is the presence of repeating amide (-CONH-) groups, which introduce hydrogen bonding between the chains. This molecular configuration is key to nylon’s strength and durability. Nylon types can be classified as aliphatic, semi-aromatic, or aromatic, depending on the backbone structure.
Nylon PA Plastic Properties
Physical Properties
- Density:Ranges from about 1.14 to 1.15 g/cm³, higher than many other thermoplastics.
- Appearance:Typically horny and tough, with a glossy surface; color can be easily customized.
- Water Absorption:High hygroscopicity, with saturation levels exceeding 3%, which can affect dimensional stability.
Mechanical Properties
- Tensile Strength:PA66, for example, reaches 80–100 MPa, about 2–3 times that of HDPE.
- Yield Strength:Comparable to its tensile strength; surpasses many common plastics like ABS.
- Impact &Fatigue Resistance:Maintains strength after repeated flexing or impact, making it suitable for moving mechanical parts.
- Wear Resistance:Low coefficient of friction and smooth surface enable continuous use without lubrication.
- Hardness:Shore D hardness around 80; retains strength at both low and elevated temperatures.
- Shrinkage:Molded parts typically shrink 1–2%, and dimensions may change with moisture uptake.
Thermal Properties
- Melting Point:Usually 215–260°C, depending on the type.
- Operating Temperature:Most grades work reliably from -40°C to 105°C.
- Heat Resistance:Outperforms many standard plastics—ordinary plastics soften at 80°C, while nylon can endure up to 140°C or more, especially when glass fiber reinforced.
Chemical &Environmental Resistance
- Chemical Resistance:Withstands oils, greases, solvents, most acids, and alkalis. However, exposure to strong acids and long-term sunlight can degrade the material.
- UV Resistance:Basic grades are susceptible to UV aging, but this can be improved with stabilizers.
- Self-Extinguishing:Nylon can be formulated to offer self-extinguishing properties.
Electrical Properties
- Insulation:Offers excellent electrical insulation and high breakdown voltage, even in humid conditions.
Machinability &Processability
- Processing:Nylon is typically injection molded or extruded, requiring pre-drying to prevent defects. Low melt viscosity allows it to fill molds quickly, supporting complex shapes and efficient cycles.
Printability
Nylon needs high extrusion temperatures (240–270°C) and a heated bed (70–100°C). It can absorb moisture quickly, so it must be kept dry before and during printing to avoid stringing and weak prints. Nylon is prone to warping and often benefits from an enclosure and bed adhesives.
Nylon Plastic Pros and Cons
Advanatges:
- Exceptional mechanical strength and rigidity, rivaling some metals.
- Outstanding wear and fatigue resistance, suitable for load-bearing and moving parts.
- Resistant to a wide range of chemicals, including fuels and lubricants.
- Self-lubricating qualities, reducing the need for external lubricants.
- Good heat resistance, especially in reinforced grades.
- Electrical insulation properties remain stable in various environments.
- Lightweight compared to metals, which is valued in automotive and aerospace applications.
- Easily dyed for aesthetic purposes.
Disadvantages:
- High water absorption, which can lead to dimensional changes and affect properties, especially in thin-walled parts.
- Suffers from UV degradation unless stabilized.
- Poor fire resistance and can emit toxic fumes when burned.
- More expensive than some common plastics like PE or PP.
- Challenging to recycle; typically categorized as plastic #7, which is not widely processed by municipal recycling systems.
- Requires careful processing, as moisture content can cause defects like air bubbles or surface streaks.
Nylon Plastic Types
Nylon is available in various forms, each with specific features:
- PA6:Made from caprolactam, offering toughness and impact resistance; widely used in automotive and consumer goods.
- PA66:Produced from hexamethylene diamine and adipic acid, it provides higher tensile strength and better heat resistance than PA6.
- PA610, PA11, PA12:These types offer differing levels of flexibility, moisture absorption, and chemical resistance for specialized uses.
- Glass-Fiber Reinforced Nylon:Enhanced strength, rigidity, and temperature resistance.
- Lubricated or Modified Grades:Additives such as sulfides further boost wear resistance and lower friction.
Nylon Plastic Applications
Nylon’s unique combination of strength, wear resistance, and processability has led to its widespread adoption:
- Textiles and Apparel:Fibers for clothing, jackets, lingerie, and carpets.
- Automotive:Gears, bushings, fuel lines, hoses, under-the-hood parts, and small actuators.
- Mechanical Components:Bearings, gears, machine parts, rollers, cable ties, and fasteners.
- Consumer Goods:Zippers, toothbrush bristles, sporting goods, tool handles, ropes, and cords.
- Electrical/Electronic:Connectors, housings, insulators for various devices.
- Medical:Suture threads, prosthetics, and gloves.
- Aerospace and Military:Parachute cords, straps, and lightweight load-bearing components.
- 3D Printing:Favored for functional prototypes, jigs, fixtures, and end-use parts due to its strength and durability.
Nylon Plastic Cost
Nylon is generally more costly than basic plastics such as PE or PP, reflecting its engineering-grade performance. Its expense is justified by the material’s high strength, durability, and broad functionality. Reinforced or specialty grades can command higher prices, and the additional need for pre-drying and careful handling can influence production costs.
Nylon Plastic Lifespan &Recycling
Nylon is selected for products that require longevity—carpets, automotive parts, and mechanical components often last for years or even decades. Its durability, however, leads to a low recycling rate, as many nylon parts remain in use for a long period and are difficult to collect and sort at end-of-life. Nylon is classified as a #7 plastic (Other), which means municipal recycling systems rarely process it. While technically recyclable, the practical recycling rate is close to zero percent, mainly due to collection challenges and contamination from additives or fiber blends.
8. ABS vs PLA vs PETG vs TPU vs ASA vs PBT vs Nylon, What are the Differences?
Here we are going to sort out the comprehensive comparison table that captures the key differences between ABS, PLA, PETG, TPU, ASA, PBT, and Nylon for 3D printing and engineering applications:
PLA vs PETG vs ABS vs ASA vs Nylon (PA), Which Is the Strongest Filament Type?
When comparing the strength of popular 3D printing filaments:PLA, PETG, ABS, ASA, Nylon (PA), and Polycarbonate (PC), it’s important to recognize that “strength” can mean different things depending on the type of stress or condition:tensile strength, resistance to bending, impact resistance, temperature durability, and more. Below is a detailed overview, integrating direct insights from testing and the properties of each material.
Tensile Strength:Which Filament Withstands the Most Pull?
Among the tested materials, polycarbonate (PC) emerges as the strongest in tensile tests, with nylon (PA) also performing very well. PLA is also relatively strong in this regard, but it tends to fracture suddenly, while nylon displays some deformation before it fails. This means that, in a scenario where the part is pulled until it breaks, polycarbonate can handle the highest load, followed by nylon and PLA. ABS, PETG, and ASA generally follow in the next tier for tensile strength.
Layer Adhesion:Strength Between Layers
Layer adhesion is crucial for 3D printed parts, especially those printed in the vertical direction, where the weakest point is often between layers. Nylon stands out for superior layer adhesion, with some nylons exhibiting similar strength in both horizontal (XY) and vertical (Z) directions. This is notable because it means nylon parts can be strong even when printed standing up. ABS and ASA are more sensitive to cooling and can have weaker layer adhesion if cooled too quickly, which is important to manage during the printing process. Polycarbonate also has good layer adhesion but may require an enclosure for best results.
Shear and Torsion:Resistance to Twisting and Sliding
Testing for shear strength (resistance to sliding forces) and torsion (twisting) shows that polycarbonate and nylon are the strongest in these categories. Reinforced versions, such as carbon fiber or glass-fiber filled types, can perform even better. PLA and ABS provide moderate resistance, while PETG and, in some cases, nylon, being more flexible, allow for more deformation under torque before breaking.
Impact Resistance:Which Material Withstands Shocks Best?
When it comes to withstanding impacts (such as a sudden blow), nylon leads the field. ABS and ASA also provide excellent impact resistance, making them suitable for parts that must absorb shocks or drops. Polycarbonate can be brittle, especially in reinforced forms, which can lead to sudden failure under impact. PLA, though sometimes tougher than PETG, is generally less impact resistant compared to nylon, ABS, and ASA.
Bending (Flexural Strength):Stiffness vs. Flexibility
For applications requiring resistance to bending, polycarbonate again proves to be the strongest filament, followed by PLA. Nylon shows the largest deformation under the same load, making it less suitable for applications demanding high stiffness, as it tends to flex and “creep” (gradually deform) over time under constant stress. For projects needing maximum stiffness, such as holders or brackets, carbon-fiber reinforced polycarbonate stands out, though it can be brittle and challenging to print.
Creep Resistance:Holding Shape Under Continuous Load
Creep resistance measures a material’s ability to maintain its shape under a constant load over time. Polycarbonate shows the least deformation under long-term loading, maintaining its original dimensions for days under stress. Nylon, on the other hand, tends to deform the most in creep tests, so it is less suitable for parts that need to hold their shape under continuous stress or weight.
Temperature Resistance:Which Filament Handles Heat Best?
For high-temperature environments, nylon stands out for its ability to maintain form and strength at elevated temperatures. Polycarbonate also scores highly in this category. PLA is the weakest here—it will deform at relatively low temperatures, such as those found inside a car on a hot day. ASA and ABS offer moderate heat resistance, with ASA often used for outdoor applications due to its combination of heat and UV resistance.
Which Filament with the Right Strength to Choose for Your Project?
- For Maximum Overall Strength:Polycarbonate (PC) is the first choice for tensile, flexural, and creep resistance, but it can be brittle in impact and is more demanding to print.
- For Impact Resistance:Nylon is the leader, followed by ABS and ASA.
- For High Temperature Environments:Nylon and PC are most suitable.
- For Stiff, Non-Flexible Parts:Carbon-fiber reinforced PC is extremely stiff, but challenging to print and may be brittle.
- For General Engineering Use:ABS, ASA, and PETG provide a good balance of durability, ease of use, and mechanical properties.
- For Layer Strength in 3D Prints:Nylon excels, with some types nearly as strong in the vertical as horizontal direction.
Note:Properties can vary across brands, blends, and reinforced versions (like carbon or glass fiber filled). Always consider the specific mechanical and environmental needs of your project.
ABS vs PLA vs PETG vs TPU vs ASA vs PBT vs Nylon, Which is the Right Filament for Your Project?
- For beginners or decorative prints:PLA offers the easiest experience with the widest range of colors.
- For functional or mechanical parts:ABS, PETG, ASA, and Nylon provide more strength, heat resistance, and durability.
- For outdoor or UV-exposed items:ASA and PETG withstand sunlight and weather far better than PLA or ABS.
- For flexibility:TPU is unmatched for prints needing stretch or shock absorption.
- For specialized engineering needs:PBT, POM, and Nylon deliver excellent performance in industrial or high-wear settings.
工业技术
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